Product ID:AMMONIUM PYRROLIDINE DITHIOCARBAMATE, A182-10
MSDS Date:04/29/1998
FSC:NIIN:Submitter:N EN
Status Code:A
MSDS Number: CKLTR

Emergency Phone: 201-796-7100

Info Phone: 201-796-7100

Cage: 1B464

Telephone: 201-796-7100

Cage: 1B464

1-PYRROLIDINECARBODITHIOIC ACID, AMMONIUM SALT

CAS: 5108-96-3

Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE: EYE: CAUSES IRRITATION. SKIN:
CAUSES IRRITATION. INGEST: INGEST OF LG AMTS MAY CAUSE
GASTROINTESTINAL IRRIT. THE TOXICOLOGICAL PROPERTIES OF THIS
SUBSTANCE HAVE NOT BEEN FULLY INVESTIGATED. INH AL: MAY CAUSE
RESPIRATORY TRACT IRRITATION. LOW HAZARD FOR USUAL INDUSTRIAL
HANDLING. THE TOXICOLOGICAL PROPERTIES OF THIS SUBSTANCE HAVE NOT
BEEN FULLY INVESTIGATED. CHRONIC: NO INFORMATION FOUND.
Effects of Overexposure:SEE HEALTH HAZARDS.

First Aid:EYES: IMMED FLUSH W/PLENTY OF WATER FOR AT LST 15 MINS,
OCCASIONALLY LIFTING UPPER & LOWER LIDS. GET MED AID. SKIN: FLUSH
W/PLENTY OF SOAP & WATER FOR AT LST 15 MINS WHILE REMOVING CONTAMD
CLTHG & SHO ES. GET MED AID IF IRRIT DEVELOPS/PERSISTS. WASH CLTHG
BEFORE REUSE. INGEST: IF CONSCIOUS & ALERT, GIVE 2-4 CUPFULS OF
MILK/WATER. NEVER GIVE ANYTHING BY MOUTH TO UNCON PERSON. GET MED
AID. INHAL: REM OVE TO FRESH AIR IMMED. IF NOT BRTHG, GIVE ARTF
RESP. IF BRTHG IS DFCLT, GIVE OXYG. GET MED AID IF COUGH/OTHER
SYMPS APPEAR. NOTES TO PHYS: TREAT SYMPTOMATICALLY & SUPPORTIVELY.

Extinguishing Media:USE WATER, DRY CHEMICAL, CHEMICAL FOAM, OR
ALCOHOL-RESISTANT FOAM. USE AGENT MOST APPROPRIATE TO EXTINGUISH
FIRE.
Fire Fighting Procedures:WEAR NIOSH APPRVD SCBA & FULL PRO ECTIVE
EQUIPMENT .
Unusual Fire/Explosion Hazard:DURING A FIRE, IRRITATING & HIGHLY TOXIC
GASES MAY BE GENERATED BY THERMAL DECOMPOSITION OR COMBUSTION. THIS
MATERIAL IN SUFFICIENT QUANTITY & REDUCED PARTICLE SIZE IS CAPABLE
OF CREATING A DUST EXPLO SION.

Spill Release Procedures:GEN INFO: USE PROPER PERSONAL PROT EQUIP AS
INDICATED IN EXPOSURE CONTROLS, PERSONAL PROT SECTION. VACUUM/SWEEP
UP MATL & PLACE INTO SUITABLE DISP CNTNR. CLEAN UP SPILLS IMMED,
OBSERVING PRECAUTIONS I N PROT EQUIP SECTION. AVOID GENERATING
DUSTY CONDITIONS. PROVIDE VENTILATION.

Handling and Storage Precautions:USE WITH ADEQUATE VENTILATION.
MINIMIZE DUST GENERATION & ACCUMULATION. AVOID CONT WITH SKIN &
EYES. AVOID INGESTION & INHALATION. STORE PROTECTED FROM AIR. WASH
CLOTHING BEFORE REUSE.
Other Precautions:STORE IN A COOL, DRY PLACE. KEEP FROM CONTACT WITH
OXIDIZING MATERIALS. KEEP CONTAINERS TIGHTLY CLOSED. DO NOT EXPOSE
TO AIR. STORE BELOW 50C.

Respiratory Protection:FOLLOW OSHA RESP REGS FOUND IN 29CFR
1910.134/EUROPEAN STD EN 149. ALWAYS USE NIOSH OR EUROPEAN EN 149
APPROVED RESPIRATOR WHEN NECESSARY.
Ventilation:FACILITIES STORING/UTILIZING MATL SHOULD BE EQUIPPED
W/EYEWASH FACILITY & SFTY SHOWER. USE ADEQ VENT TO KEEP AIRBORNE
CONCS LOW.
Protective Gloves:IMPERVIOUS GLOVES .
Eye Protection:ANSI APPROVED CHEMICAL WORKERS GOGGLES .
Other Protective Equipment:EYE WASH & DELUGE SHOWER MEETING ANSI DESIGN
CRITERIA . WEAR APPROP GLOVES TO PVNT SKIN EXPOSURE. WEAR APPROP
PROT CLTHG TO MINIMIZE CONT WITH SKIN.
Work Hygienic Practices:WASH CLOTHING BEFORE USE.
Supplemental Safety and Health

Melt/Freeze Pt:=155.C, 311.F
Decomp Temp:>155.C, 311.F
Vapor Pres:NEGLIGIBLE
Evaporation Rate & Reference:NEGLIGIBLE
Solubility in Water:SOLUBLE
Appearance and Odor:SOLID YELLOW. NO ODOR.

Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS.
Stability Condition to Avoid:STABLE. HOWEVER, MAY DECOMPOSE IF HEATED.
INCOMPATIBLE MATERIALS, EXPOSURE TO AIR, TEMPERATURES ABOVE 55C.
Hazardous Decomposition Products:NITROGEN OXIDES, CARBON MONOXIDE,
OXIDES OF SULFUR, CARBON DIOXIDE.

Waste Disposal Methods:DISPOSE OF IN MANNER CONSISTENT WITH FEDERAL,
STATE, AND LOCAL REGS. RCRA D-SERIES MAX CONC OF CONTAMINANTS: NONE
LISTED. RCRA D,F,P, & U SERIES: NONE LISTED. NOT LISTED AS A
MATERIAL BANNED FROM LAND DISPOSAL ACCORDING TO RCRA.

Toxicological Information:RTECS#: CAS# 5108-96-3 UNLISTED. LD50/LC50:
NOT AVAILABLE. CARCINOGENICITY: 1-PYRROLIDINECARBODITHIOIC ACID
AMMONIUM SALT - NOT LISTED BY ACGIH, IARC, NIOSH, NTP, OR OSHA.
EPIDEMIOLOGY, TERATOGENICITY , REPRODUCTIVE EFFECTS, NEUROTOXICITY,
MUTAGENICITY & OTHER STUDIES: NO INFORMATION AVAILABLE.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Ecological:ECOTOXICITY, ENVIRONMENTAL FATE, PHYSICAL/CHEMICAL & OTHER:
NOT AVAILABLE.

Transport Information:US DOT, IMO, IATA, RID/ADR, CANADIAN TDG: NO
INFORMATION AVAILABLE.

SARA Title III Information:SECTION 302 (RQ): NONE OF CHEMS IN MATL HAVE
RQ. SECTION 302 (TPQ): NONE OF CHEMS IN THIS PROD HAVE TPQ. SARA
CODES: CAS # 5108-96-3: ACUTE, CHRONIC. SECTION 313: NO CHEMS ARE
REPORTABLE UNDER SECTION 313.
Federal Regulatory Information:TSCA CAS# 5108-96-3 IS LISTED ON TSCA
INVENTORY. HLTH & SFTY RPTG LIST: NONE OF CHEMS ARE ON HLTH & SFTY
RPTG LIST. CHEM TEST RULES: NONE OF CHEMS IN PROD ARE UNDER CHEM
TEST RULE. SECTION 12B:NONE OF CHEMS ARE LISTED UNDER TSCA SECTION
12B. TSCA SIGNIFICANT NEW USE RULE: NONE OF CHEMS IN MATL HAVE SNUR
UNDER TSCA. CLEAN AIR ACT: THIS MATL DOES NOT CNTN ANY HAZ AIR
POLLUTANTS, CLASS 1 OZONE DEPLET ORS OR CLASS 2 OZONE DEPLETORS.
CLEAN WATER ACT: NONE OF CHEMS IN PROD ARE LISTED AS HAZ SUBSTANCES
OR PRIORITY POLLUTANTS UNDER CWA. OSHA: NONE OF CHEMS LISTED ARE
CONSIDERED HIGHLY HAZ BY OSHA.
State Regulatory Information:1-PYRROLIDINECARBODITHIOIC ACID AMMONIUM
SALT IS NOT PRESENT ON STATE LISTS FROM CA, PA, MN, MA, FL, OR NJ.
CALIFORNIA NO SIGNIFICANT RISK LEVEL: NONE OF CHEMS IN PROD ARE
LISTED. EUROPEAN/INTERNATION AL REGS: EUROPEAN LABELING I/A/W EC
DIRECTIVES. HAZARD SYMBOLS: XI. RISK PHRASES: R 36/38 IRRITATING TO
EYES & SKIN. SFTY PHRASES: S 24/25 AVOID CONT W/SKIN & EYES. WGK
(WATER DANGER/PROT): CAS# 5108- 96-3: NO INFO AVAIL. CANADA: CAS#
5108-96-3 IS LISTED ON CANADA'S INGRED DISCLOSURE LIST.